Extended EDTA Bola-Amphiphile: Putrescine-Based 2G Dendron Functionalized with Perylene Diimide
Singh P, Hirsch A (2021)
Publication Type: Journal article
Publication year: 2021
Journal
Book Volume: 6
Pages Range: 12981-12984
Journal Issue: 45
Abstract
We have synthesized and characterized putrescine based 2G dendron bearing oligocarboxylic acid as hydrophilic groups (protected as tert-butyl group) at peripheral positions. The multi-step synthesis of 2G dendron has been carried out through orthogonal protection-deprotection strategy. This putrescine based 2G dendron is further utilized for N-Imide functionalization of perylene dianhydride through imidization reaction to obtained tert-butyl-protected PDI 2 followed by acidic deprotection to furnish highly water-soluble bola-amphiphile PDI 1. The newly synthesized compounds were characterized by NMR-spectroscopy, Mass spectrometry, IR as well as by elemental analysis. The PDI 1 showed increased water solubility in acidic and basic mediums.
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APA:
Singh, P., & Hirsch, A. (2021). Extended EDTA Bola-Amphiphile: Putrescine-Based 2G Dendron Functionalized with Perylene Diimide. ChemistrySelect, 6(45), 12981-12984. https://dx.doi.org/10.1002/slct.202102933
MLA:
Singh, Prabhpreet, and Andreas Hirsch. "Extended EDTA Bola-Amphiphile: Putrescine-Based 2G Dendron Functionalized with Perylene Diimide." ChemistrySelect 6.45 (2021): 12981-12984.
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