Interaction between Ionic Liquids and a Pt(111) Surface Probed by Coadsorbed CO as a Test Molecule

Eschenbacher R, Schuschke C, Bühlmeyer H, Taccardi N, Wasserscheid P, Bauer T, Xu T, Libuda J (2021)


Publication Type: Journal article

Publication year: 2021

Journal

Pages Range: 10079-10085

DOI: 10.1021/acs.jpclett.1c02983

Abstract

We used temperature-programmed infrared reflection absorption spectroscopy (TP-IRAS) to study the desorption behavior of CO on Pt(111) coadsorbed with four kinds of ionic liquids (ILs), namely 1-butyl-1-methyl-pyrrolidinium-bis(trifluoromethylsulfonyl)imide ([C4C1Pyr][NTf2]), 1-ethyl-3-methyl-imidazolium-bis(trifluoromethylsulfonyl)imide ([C2C1Im][NTf2]), 1-butyl-1-methyl-pyrrolidinium-trifluoro-methanesulfonate ([C4C1Pyr][OTf]), and 1-butyl-1-methyl-pyrrolidinium-hexafluorophosphate ([C4C1Pyr][PF6]). We found that CO desorbs earlier from a Pt(111) surface with coadsorbed ILs than without. In addition, the CO desorption temperature varies between different types of coadsorbed ILs, which follows the order: [C4C1Pyr][PF6] (365 K) > [C4C1Pyr][NTf2] (362 K) > [C2C1Im][NTf2] (352 K) > [C4C1Pyr][OTf] (348 K). We ascribe the difference in CO desorption temperature to the different interaction strength between ILs and the Pt(111) surface. A stronger IL-Pt(111) interaction leads to a lower CO desorption temperature. We suggest that TP-IRAS experiments of CO coadsorbed with ILs can be a useful method to aid the characterization of the interaction strength between ILs and metal surfaces such as Pt(111).

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How to cite

APA:

Eschenbacher, R., Schuschke, C., Bühlmeyer, H., Taccardi, N., Wasserscheid, P., Bauer, T.,... Libuda, J. (2021). Interaction between Ionic Liquids and a Pt(111) Surface Probed by Coadsorbed CO as a Test Molecule. Journal of Physical Chemistry Letters, 10079-10085. https://dx.doi.org/10.1021/acs.jpclett.1c02983

MLA:

Eschenbacher, Roman, et al. "Interaction between Ionic Liquids and a Pt(111) Surface Probed by Coadsorbed CO as a Test Molecule." Journal of Physical Chemistry Letters (2021): 10079-10085.

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