Expanding manganese(iv) aqueous chemistry: unusually stable water-soluble hexahydrazide clathrochelate complexes

Shylin SI, Pogrebetsky JL, Husak AO, Bykov D, Mokhir A, Hampel F, Shova S, Ozarowski A, Gumienna-Kontecka E, Fritsky IO (2021)

Publication Type: Journal article

Publication year: 2021

Journal

Chemical Communications Royal Society of Chemistry

DOI: 10.1039/d1cc04870h

Abstract

Mn cage complexes are rare, and the ones successfully isolated in the solid state are not stable in water and organic solvents. Herein, we present the first report of mononuclear Mn clathrochelates, in which the encapsulated metal exists in the oxidation state +4. The complexes are extremely stable in the crystalline state and in solutions and show rich redox chemistry.

Authors with CRIS profile

Andriy Mokhir Professur für Organische Chemie Frank Hampel Lehrstuhl für Organische Chemie I

Involved external institutions

Taras Shevchenko National University of Kyiv (KNU) / Київський національний університет імені Тараса Шевченка

Ukraine (UA) Oak Ridge National Laboratory

United States (USA) (US) "Petru Poni" Institute of Macromolecular Chemistry

Romania (RO) Florida State University (FSU)

United States (USA) (US) University of Wroclaw / Uniwersytet Wrocławski

Poland (PL)

How to cite

APA:

Shylin, S.I., Pogrebetsky, J.L., Husak, A.O., Bykov, D., Mokhir, A., Hampel, F.,... Fritsky, I.O. (2021). Expanding manganese(iv) aqueous chemistry: unusually stable water-soluble hexahydrazide clathrochelate complexes. Chemical Communications. https://dx.doi.org/10.1039/d1cc04870h

MLA:

Shylin, Sergii I., et al. "Expanding manganese(iv) aqueous chemistry: unusually stable water-soluble hexahydrazide clathrochelate complexes." Chemical Communications (2021).

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