A lead(II) toluene complex

Messelberger J, Pinter P, Heinemann FW, Munz D (2021)

Publication Type: Journal article

Publication year: 2021

Journal

Mendeleev Communications Elsevier / Royal Society of Chemistry

Book Volume: 31

Pages Range: 471-474

Journal Issue: 4

DOI: 10.1016/j.mencom.2021.07.011

Abstract

A well defined intermolecular toluene complex of lead(ii) supported by a pincer-type saNHC (saturated N-heterocyclic carbene) ligand was prepared through deprotonation of the bis(irnidazolinium) salt with Pb[N(SiMe3)(2)](2) or metalation of the free carbene and subsequent salt metathesis with Tl(OTf), followed by crystallization from toluene. Combined computational and experimental results indicate that noncovalent interactions with the lead atom (sigma-hole type interaction, dispersion) and the diisopropylphenyl side groups of the ligand (dispersion) stabilize the complex.

Authors with CRIS profile

Frank Wilhelm Heinemann Lehrstuhl für Anorganische und Allgemeine Chemie

Involved external institutions

Universität des Saarlandes (UdS) DE Germany (DE)

How to cite

APA:

Messelberger, J., Pinter, P., Heinemann, F.W., & Munz, D. (2021). A lead(II) toluene complex. Mendeleev Communications, 31(4), 471-474. https://dx.doi.org/10.1016/j.mencom.2021.07.011

MLA:

Messelberger, Julian, et al. "A lead(II) toluene complex." Mendeleev Communications 31.4 (2021): 471-474.

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