Decatungstate-Photocatalyzed Addition of Lactones to [60]Fullerene

Malliaros NG, Kellner I, Drewello T, Orfanopoulos M (2021)

Publication Type: Journal article

Publication year: 2021

Journal

Journal of Organic Chemistry American Chemical Society

DOI: 10.1021/acs.joc.1c00954

Abstract

A new, one step functionalization of C60 with lactones has been developed. This photochemical approach utilizes a variety of lactonyl radicals deriving from lactones through a hydrogen atom abstraction process mediated by tetrabutylammonium decatungstate [(n-Bu4N)4W10O32]. This reaction provides access to a previously unknown class of materials, namely 1-lactonyl-2-hydro[60]fullerenes. A mechanism for this new reaction has been proposed based mainly on the structure of reaction products and deuterium-incorporated experiments.

Authors with CRIS profile

Ina Kellner Lehrstuhl für Physikalische Chemie I Thomas Drewello Professur für Physikalische Chemie

Involved external institutions

University of Crete / Πανεπιστήμιο Κρήτης GR Greece (GR)

How to cite

APA:

Malliaros, N.G., Kellner, I., Drewello, T., & Orfanopoulos, M. (2021). Decatungstate-Photocatalyzed Addition of Lactones to [60]Fullerene. Journal of Organic Chemistry. https://dx.doi.org/10.1021/acs.joc.1c00954

MLA:

Malliaros, Nikitas G., et al. "Decatungstate-Photocatalyzed Addition of Lactones to [60]Fullerene." Journal of Organic Chemistry (2021).

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