Isolation of a [Fe(CO)4]2--Bridged Diuranium Complex Obtained via Reduction of Fe(CO)5with Uranium(III)

Ward RJ, Pividori DM, Carpentier A, Tarlton ML, Kelley SP, Maron L, Meyer K, Walensky JR (2021)

Publication Type: Journal article

Publication year: 2021

Journal

Organometallics American Chemical Society

DOI: 10.1021/acs.organomet.1c00205

Abstract

Treatment of the U(III) complex, [(C5Me5)2U(OMes)(THF)], Mes = 2,4,6-Me3C6H2, with Fe(CO)5 forms [{(C5Me5)2(MesO)U}2(μ2-(OC)2Fe(CO)2)] with the bridging, tetrahedral Fe(CO)4 moiety. This complex has been studied using 1H NMR, IR vibrational, UV-vis electronic absorption, and zero-field 57Fe Mössbauer spectroscopy as well as single-crystal X-ray diffraction analysis, magnetic measurements, and DFT calculations.

Authors with CRIS profile

Daniel Maximilian Pividori Lehrstuhl für Anorganische und Allgemeine Chemie Karsten Meyer Lehrstuhl für Anorganische und Allgemeine Chemie

Involved external institutions

University of Missouri-Columbia (Mizzou) US United States (USA) (US) Université Toulouse III - Paul Sabatier FR France (FR)

How to cite

APA:

Ward, R.J., Pividori, D.M., Carpentier, A., Tarlton, M.L., Kelley, S.P., Maron, L.,... Walensky, J.R. (2021). Isolation of a [Fe(CO)4]2--Bridged Diuranium Complex Obtained via Reduction of Fe(CO)5with Uranium(III). Organometallics. https://dx.doi.org/10.1021/acs.organomet.1c00205

MLA:

Ward, Robert J., et al. "Isolation of a [Fe(CO)4]2--Bridged Diuranium Complex Obtained via Reduction of Fe(CO)5with Uranium(III)." Organometallics (2021).

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