(thf)(2)Ln(Ge-9{Si(SiMe3)(3)}(3))(2) (Ln = Eu, Sm): the first coordination of metalloid germanium clusters to lanthanides

Klementyeva SV, Schrenk C, Zhang M, Khusniyarov M, Schnepf A (2021)

Publication Type: Journal article

Publication year: 2021

Journal

Chemical Communications Royal Society of Chemistry

DOI: 10.1039/d1cc01151k

Abstract

We report the synthesis, structure and magnetic properties of the first rare earth complexes of metalloid group 14 clusters [(thf)(2)Ln(Ge(9)Hyp(3))(2)] (Ln = Eu, Sm, Hyp = Si(SiMe3)(3)). X-Ray crystallographic analysis and DFT calculations reveal a novel eta(2)-coordination mode of the Ge(9)Hyp(3) units and a slight distortion of the Ge-9 cage.

Authors with CRIS profile

Minghui Zhang Naturwissenschaftliche Fakultät Marat Khusniyarov Lehrstuhl für Bioanorganische Chemie

Involved external institutions

Eberhard Karls Universität Tübingen DE Germany (DE)

How to cite

APA:

Klementyeva, S.V., Schrenk, C., Zhang, M., Khusniyarov, M., & Schnepf, A. (2021). (thf)(2)Ln(Ge-9{Si(SiMe3)(3)}(3))(2) (Ln = Eu, Sm): the first coordination of metalloid germanium clusters to lanthanides. Chemical Communications. https://dx.doi.org/10.1039/d1cc01151k

MLA:

Klementyeva, Svetlana V., et al. "(thf)(2)Ln(Ge-9{Si(SiMe3)(3)}(3))(2) (Ln = Eu, Sm): the first coordination of metalloid germanium clusters to lanthanides." Chemical Communications (2021).

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