Hexa-: Peri-hexabenzocoronene decorated with an allenylidene ruthenium complex-Almost a flyswatter

Lorenz R, Reger D, Weller R, Jux N, Burzlaff N (2020)

Publication Type: Journal article

Publication year: 2020

Journal

Dalton Transactions Royal Society of Chemistry

Book Volume: 49

Pages Range: 13134-13141

Journal Issue: 37

DOI: 10.1039/d0dt02729d

Abstract

Carbon-rich ruthenium allenylidene complexes bearing either a hexaarylbenzene (HAB) or a hexa-peri-hexabenzocoronene (HBC) substituent were synthesised. This was achieved via the corresponding propargyl alcohols with HAB and HBC substituents, which were accessible via 3 or 4 step reaction cascades. Reaction of the propargyl alcohols HCC(OH)Ph(HAB) and HCC(OH)Ph(HBC) with [RuCl(η5-C5H5)(PPh3)2] yielded the complexes [Ru(η5-C5H5)(CCC(HAB)(Ph))(PPh3)2]PF6 and [Ru(η5-C5H5)(CCC(HBC)(Ph))(PPh3)2]PF6. The latter of which shows interesting π-π-stacking behaviour in the solid state as well as aggregation in solution.

Authors with CRIS profile

Rebecca Kleeberger Professur für Anorganische Chemie David Reger Naturwissenschaftliche Fakultät Ruth Weller Sonderforschungsbereich 953/3 Synthetische Kohlenstoffallotrope Norbert Jux Naturwissenschaftliche Fakultät Nicolai Burzlaff Professur für Anorganische Chemie

How to cite

APA:

Lorenz, R., Reger, D., Weller, R., Jux, N., & Burzlaff, N. (2020). Hexa-: Peri-hexabenzocoronene decorated with an allenylidene ruthenium complex-Almost a flyswatter. Dalton Transactions, 49(37), 13134-13141. https://dx.doi.org/10.1039/d0dt02729d

MLA:

Lorenz, Rebecca, et al. "Hexa-: Peri-hexabenzocoronene decorated with an allenylidene ruthenium complex-Almost a flyswatter." Dalton Transactions 49.37 (2020): 13134-13141.

BibTeX: Download