Synthesis of an All-Ferric Cuboidal Iron–Sulfur Cluster [FeIII4S4(SAr)4]

Moula G, Matsumoto T, Miehlich M, Meyer K, Tatsumi K (2018)

Publication Type: Journal article

Publication year: 2018

Journal

Angewandte Chemie International Edition Wiley

Book Volume: 57

Pages Range: 11594-11597

Journal Issue: 36

DOI: 10.1002/anie.201803679

Abstract

An unprecedented, super oxidized all-ferric iron–sulfur cubanoid cluster with all terminal thiolates, Fe4S4(STbt)4 (3) [Tbt=2,4,6-tris{bis(trimethylsilyl)methyl}phenyl], has been isolated from the reaction of the bis-thiolate complex Fe(STbt)2 (2) with elemental sulfur. This cluster 3 has been characterized by X-ray crystallography, zero-field 57Fe Mössbauer spectroscopy, cyclic voltammetry, and other relevant physico-chemical methods. Based on all the data, the electronic ground state of the cluster has been assigned to be Stot=0.

Authors with CRIS profile

Matthias Miehlich Lehrstuhl für Anorganische und Allgemeine Chemie Karsten Meyer Lehrstuhl für Anorganische und Allgemeine Chemie

Involved external institutions

Nagoya University / 名古屋大学 JP Japan (JP)

How to cite

APA:

Moula, G., Matsumoto, T., Miehlich, M., Meyer, K., & Tatsumi, K. (2018). Synthesis of an All-Ferric Cuboidal Iron–Sulfur Cluster [FeIII4S4(SAr)4]. Angewandte Chemie International Edition, 57(36), 11594-11597. https://dx.doi.org/10.1002/anie.201803679

MLA:

Moula, Golam, et al. "Synthesis of an All-Ferric Cuboidal Iron–Sulfur Cluster [FeIII4S4(SAr)4]." Angewandte Chemie International Edition 57.36 (2018): 11594-11597.

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