Epitaxial Metal Halide Perovskites by Inkjet-Printing on Various Substrates

Sytnyk M, Yousefi-Amin AA, Freund T, Prihoda A, Götz K, Unruh T, Harreiß C, Will J, Spiecker E, Levchuk J, Osvet A, Brabec C, Künecke U, Wellmann P, Volobuev VV, Korczak J, Szczerbakow A, Story T, Simbrunner C, Springholz G, Wechsler D, Lytken O, Lotter S, Kampmann F, Maultzsch J, Singh K, Voznyy O, Heiß W (2020)

Publication Type: Journal article

Publication year: 2020

Journal

Advanced Functional Materials Wiley-VCH Verlag

Book Volume: 30

Article Number: ARTN 2004612

Journal Issue: 43

DOI: 10.1002/adfm.202004612

Abstract

Metal-halide-perovskites revolutionized the field of thin-film semiconductor technology, due to their favorable optoelectronic properties and facile solution processing. Further improvements of perovskite thin-film devices require structural coherence on the atomic scale. Such perfection is achieved by epitaxial growth, a method that is based on the use of high-end deposition chambers. Here epitaxial growth is enabled via a approximate to 1000 times cheaper device, a single nozzle inkjet printer. By printing, single-crystal micro- and nanostructure arrays and crystalline coherent thin films are obtained on selected substrates. The hetero-epitaxial structures of methylammonium PbBr(3)grown on lattice matching substrates exhibit similar luminescence as bulk single crystals, but the crystals phase transitions are shifted to lower temperatures, indicating a structural stabilization due to interfacial lattice anchoring by the substrates. Thus, the inkjet-printing of metal-halide perovskites provides improved material characteristics in a highly economical way, as a future cheap competitor to the high-end semiconductor growth technologies.

Authors with CRIS profile

Mykhailo Sytnyk Institute Materials for Electronics and Energy Technology (i-MEET) Tim Freund Professur für Werkstoffwissenschaften (Werkstoffe der Elektrotechnik) Annemarie Prihoda Professur für Nanomaterialcharakterisierung (Streumethoden) Klaus Götz Lehrstuhl für Kristallographie und Strukturphysik Tobias Unruh Professur für Nanomaterialcharakterisierung (Streumethoden) Christina Harreiß Sonderforschungsbereich 953/3 Synthetische Kohlenstoffallotrope Johannes Will Lehrstuhl für Kristallographie und Strukturphysik Erdmann Spiecker Lehrstuhl für Werkstoffwissenschaften (Mikro- und Nanostrukturforschung) Andres Osvet Institute Materials for Electronics and Energy Technology (i-MEET) Christoph Brabec Institute Materials for Electronics and Energy Technology (i-MEET) Ulrike Künecke Institute Materials for Electronics and Energy Technology (i-MEET) Peter Wellmann Professur für Werkstoffwissenschaften (Werkstoffe der Elektrotechnik) Daniel Wechsler Lehrstuhl für Physikalische Chemie II Ole Lytken Lehrstuhl für Physikalische Chemie II Wolfgang Heiß Professur für Werkstoffwissenschaften (lösungsprozessierte Halbleitermaterialien)

Additional Organisation(s)

Lehrstuhl für Werkstoffwissenschaften (Mikro- und Nanostrukturforschung) Graduiertenkolleg 2495 Energiekonvertierungssysteme: von Materialien zu Bauteilen (Energy Conversion Systems: From Materials to Devices) Interdisziplinäres Zentrum, Center for Nanoanalysis and Electron Microscopy (CENEM) Graduiertenkolleg 1896/2 In situ Mikroskopie mit Elektronen, Röntgenstrahlen und Rastersonden

Related research project(s)

In-situ Characterization of Nanomaterials with Electrons, X-rays/Neutrons and Scanning Probes (GRK 1896) Oct. 1, 2013 - Sept. 30, 2022

Involved external institutions

Johannes Kepler Universität (JKU) Linz AT Austria (AT) University of Toronto CA Canada (CA) Institute of Physics (IFPAN) / Instytut Fizyki PAN PL Poland (PL)

How to cite

APA:

Sytnyk, M., Yousefi-Amin, A.A., Freund, T., Prihoda, A., Götz, K., Unruh, T.,... Heiß, W. (2020). Epitaxial Metal Halide Perovskites by Inkjet-Printing on Various Substrates. Advanced Functional Materials, 30(43). https://dx.doi.org/10.1002/adfm.202004612

MLA:

Sytnyk, Mykhailo, et al. "Epitaxial Metal Halide Perovskites by Inkjet-Printing on Various Substrates." Advanced Functional Materials 30.43 (2020).

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