Oxidized Hemithioindigo Photoswitches—Influence of Oxidation State on (Photo)physical and Photochemical Properties
Köttner L, Schildhauer M, Wiedbrauk S, Mayer P, Dube H (2020)
Publication Type: Journal article
Publication year: 2020
Journal
Abstract
The photophysical and photochemical properties of sulfoxide and sulfone derivatives of hemithioindigo photoswitches are scrutinized and compared to the unoxidized parent chromophores. Oxidation results in significantly blue-shifted absorptions and mostly reduction of photochromism while thermal stabilities of individual isomers remain largely unaltered. Effective photoswitching takes place at shorter wavelengths compared to parent hemithioindigos and high isomeric yields can be obtained reversibly in the respective photostationary states. Reversible solid-state photoswitching is observed for a twisted sulfone derivative accompanied by visible color changes. These results establish oxidized hemithioindigo photoswitches as promising and versatile tools for robust light-control of molecular behavior for a wide range of applications.
Authors with CRIS profile
Involved external institutions
Germany (DE)How to cite
APA:
Köttner, L., Schildhauer, M., Wiedbrauk, S., Mayer, P., & Dube, H. (2020). Oxidized Hemithioindigo Photoswitches—Influence of Oxidation State on (Photo)physical and Photochemical Properties. Chemistry - A European Journal. https://dx.doi.org/10.1002/chem.202002176
MLA:
Köttner, Laura, et al. "Oxidized Hemithioindigo Photoswitches—Influence of Oxidation State on (Photo)physical and Photochemical Properties." Chemistry - A European Journal (2020).
BibTeX: Download