Modeling the effect of the addition of alumina on structural characteristics and tensile deformation response of aluminosilicate glasses

Benitez T, Rivas Murillo JS, de Ligny D, Travitzky N, Novaes de Oliveira AP, Hotza D (2020)

Publication Type: Journal article

Publication year: 2020

Journal

Ceramics International Elsevier

DOI: 10.1016/j.ceramint.2020.05.273

Abstract

Aluminosilicate glasses, xAl2O3-(1-x)SiO2 with variable molar ratio 0 ≤ x ≤ 60%, were modeled by molecular dynamics (MD) in order to investigate the structural characteristics such as: coordination number and pair-angle distribution functions responsible for their mechanical performance. MD simulations showed that Si atoms coordinated to four O atoms are independently of the chemical composition. The number of O atoms coordinated to two decreased as the amount of Al2O3 is increased, while the opposite happened to O atoms coordinated to three. Al atoms coordinated to four O atoms were reduced as the amount of Al2O3 increases, whereas Al atoms coordinated to five O atoms were increased. Moreover, pair distribution function (PDF) study confirmed that the addition of Al2O3 causes densification of the aluminosilicate samples and, angle distribution function (ADF) corroborated PDF results and explained intermediate and long-range disorder structures of glasses. Assessment of the structural damage under uniaxial tension showed that aluminosilicate glasses are more capable of withstanding deformation without total structural failure than pure silica glasses.

Authors with CRIS profile

Dominique de Ligny Professur für Werkstoffwissenschaften (Glas und Keramik) Nahum Travitzky Lehrstuhl für Glas und Keramik

Involved external institutions

Federal University of Santa Catarina / Universidade Federal de Santa Catarina (UFSC) BR Brazil (BR) AGP de Colombia S.A CO Colombia (CO)

How to cite

APA:

Benitez, T., Rivas Murillo, J.S., de Ligny, D., Travitzky, N., Novaes de Oliveira, A.P., & Hotza, D. (2020). Modeling the effect of the addition of alumina on structural characteristics and tensile deformation response of aluminosilicate glasses. Ceramics International. https://dx.doi.org/10.1016/j.ceramint.2020.05.273

MLA:

Benitez, Tobias, et al. "Modeling the effect of the addition of alumina on structural characteristics and tensile deformation response of aluminosilicate glasses." Ceramics International (2020).

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