Kessler F, Sarfert-Gast W, Kuhlmann L, Ise M, Heinemann FW (2020)
Publication Type: Journal article
Publication year: 2020
Herein we describe the compatibility of 2-(trifluoromethyl)-2,3,3,3-tetrafluoropropane nitrile, an insulating gas for gas-insulated equipment, with aluminum, silver and copper. In an autoclave metal samples, oxygen, the gaseous 2-(trifluoromethyl)-2,3,3,3-tetrafluoropropane nitrile and a small amount of water were mixed at elevated pressure and heated up to 225 °C for several weeks. When Cu was present a multi-step gas phase reaction occurred, and single crystals of a copper complex were isolated. The square planar copper(II) complex contains two perfluorinated N-acylamidine ligands. The structure of the complex was obtained by single-crystal X-ray diffraction.
APA:
Kessler, F., Sarfert-Gast, W., Kuhlmann, L., Ise, M., & Heinemann, F.W. (2020). Compatibility of a Gaseous Dielectric with Al, Ag, and Cu and Gas-Phase Synthesis of a New N-Acylamidine Copper Complex. European Journal of Inorganic Chemistry. https://dx.doi.org/10.1002/ejic.202000213
MLA:
Kessler, Florian, et al. "Compatibility of a Gaseous Dielectric with Al, Ag, and Cu and Gas-Phase Synthesis of a New N-Acylamidine Copper Complex." European Journal of Inorganic Chemistry (2020).
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