Highly Efficient and Reversible Covalent Patterning of Graphene: 2D-Management of Chemical Information

Wei T, Kohring M, Chen M, Yang S, Weber HB, Hauke F, Hirsch A (2020)


Publication Type: Journal article

Publication year: 2020

Journal

DOI: 10.1002/anie.201914088

Abstract

Patterned graphene-functionalization with a tunable degree of functionalization can tailor the properties of graphene. Here, we present a new reductive functionalization approach combined with lithography rendering patterned graphene-functionalization easily accessible. Two types of covalent patterning of graphene were prepared and their structures were unambiguously characterized by statistical Raman spectroscopy together with scanning electron microscopy/energy-dispersive X-ray spectroscopy (SEM-EDS). The reversible defunctionalization processes, as revealed by temperature-dependent Raman spectroscopy, enable the possibility to accurately modulate the degree of functionalization by annealing. This allows for the management of chemical information through complete write/store/erase cycles. Based on our strategy, controllable and efficient patterning graphene-functionalization is no longer a challenge and facilitates the development of graphene-based devices.

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How to cite

APA:

Wei, T., Kohring, M., Chen, M., Yang, S., Weber, H.B., Hauke, F., & Hirsch, A. (2020). Highly Efficient and Reversible Covalent Patterning of Graphene: 2D-Management of Chemical Information. Angewandte Chemie International Edition. https://doi.org/10.1002/anie.201914088

MLA:

Wei, Tao, et al. "Highly Efficient and Reversible Covalent Patterning of Graphene: 2D-Management of Chemical Information." Angewandte Chemie International Edition (2020).

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