Aryl Radical Selectivity in Biphasic Systems

Altmann LM, Fürst M, Gans E, Zantop V, Pratsch G, Heinrich M (2020)

Publication Type: Journal article

Publication year: 2020

Journal

Organic Letters American Chemical Society

DOI: 10.1021/acs.orglett.9b04237

Abstract

Aryl radicals generated in the aqueous phase of biphasic mixtures have-regardless of a comparably low polarity- A strong preference to react with aromatic substrates in the aqueous phase and not to undergo phase-transfer into a lipophilic phase, independent from the presence of a surfactant. These results represent an important prerequisite toward future studies in biological systems, which typically consist of various compartments of either hydrophilic or lipophilic character.

Authors with CRIS profile

Lisa-Marie Altmann Lehrstuhl für Pharmazeutische Chemie Michael Fürst Professur für Pharmazeutische Chemie Eva Gans Lehrstuhl für Pharmazeutische Chemie Gerald Pratsch Professur für Pharmazeutische Chemie Markus Heinrich Professur für Pharmazeutische Chemie

How to cite

APA:

Altmann, L.-M., Fürst, M., Gans, E., Zantop, V., Pratsch, G., & Heinrich, M. (2020). Aryl Radical Selectivity in Biphasic Systems. Organic Letters. https://dx.doi.org/10.1021/acs.orglett.9b04237

MLA:

Altmann, Lisa-Marie, et al. "Aryl Radical Selectivity in Biphasic Systems." Organic Letters (2020).

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