Toy swords revisited: identification of additional odour-active contaminants

Wiedmer C, Velasco-Schön C, Büttner A (2019)


Publication Type: Journal article

Publication year: 2019

Journal

DOI: 10.1007/s00003-019-01253-1

Abstract

Odorants related to offensive odours in three children’s toy swords were identified and characterized by human sensory and chemical analyses. Samples were initially evaluated by a trained sensory panel. Panellists reported unpleasant smells in all samples that were dominated by mothball-like, phenolic and rubber-like notes and additionally almond-like and fatty notes. The odorants from the samples were then extracted using dichloromethane and subsequent solvent-assisted flavour evaporation distillation. Enriched distillates were then analysed by means of single and two-dimensional gas chromatography–mass spectrometry/olfactometry. An additional screening analysis for polycyclic aromatic hydrocarbons was also performed on all samples. The most predominant odorants identified in the samples were naphthalene, 1- and 2-methylnaphthalene and diverse dimethylnaphthalene isomers with gasoline-like smells. Acetophenone, with an almond-like, flowery smell, was also detected. Furthermore, the phenolic/leather-like smelling substances 3-ethylphenol, 3-hydroxyacetophenone, and 3-methoxyacetophenone were identified in one sample.

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APA:

Wiedmer, C., Velasco-Schön, C., & Büttner, A. (2019). Toy swords revisited: identification of additional odour-active contaminants. Journal of Consumer Protection and Food Safety. https://doi.org/10.1007/s00003-019-01253-1

MLA:

Wiedmer, Christoph, Cristina Velasco-Schön, and Andrea Büttner. "Toy swords revisited: identification of additional odour-active contaminants." Journal of Consumer Protection and Food Safety (2019).

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