Reversible multi-electron storage in dual-site redox-active supramolecular cages

Plessius R, Orth N, Ivanovic-Burmazovic I, Siegler MA, Reek JNH, Van Der Vlugt JI (2019)

Publication Type: Journal article

Publication year: 2019

Journal

Chemical Communications Royal Society of Chemistry

Book Volume: 55

Pages Range: 12619-12622

Journal Issue: 84

DOI: 10.1039/c9cc07138e

Abstract

M6L4¹²⁺ supramolecular cages 3a and 3b (M = Pd, Pt), soluble in organic solvents, contain two different ligand-centered redox sites that enable the reversible storage of up to 16 electrons, as probed by CV, UV/vis spectro-electrochemistry (SEC-UV/Vis), bulk electrolysis and EPR. Encapsulation of a B12F12^2- anion is confirmed by ¹H, ¹⁹F NMR and ¹⁹F DOSY NMR spectroscopy and mass spectrometry.

Authors with CRIS profile

Nicole Orth Lehrstuhl für Bioanorganische Chemie Ivana Ivanovic-Burmazovic Lehrstuhl für Bioanorganische Chemie

Involved external institutions

University of Amsterdam

Netherlands (NL) Johns Hopkins University (JHU)

United States (USA) (US)

How to cite

APA:

Plessius, R., Orth, N., Ivanovic-Burmazovic, I., Siegler, M.A., Reek, J.N.H., & Van Der Vlugt, J.I. (2019). Reversible multi-electron storage in dual-site redox-active supramolecular cages. Chemical Communications, 55(84), 12619-12622. https://dx.doi.org/10.1039/c9cc07138e

MLA:

Plessius, Raoul, et al. "Reversible multi-electron storage in dual-site redox-active supramolecular cages." Chemical Communications 55.84 (2019): 12619-12622.

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