Stabilization of the morphotropic phase boundary in (1 − x)Bi0.5Na0.5TiO3–xBaTiO3 ceramics through two alternative synthesis pathways

Prado A, Ramajo L, Camargo J, del Campo A, Öchsner PE, Rubio-Marcos F, Castro M (2019)


Publication Type: Journal article

Publication year: 2019

Journal

Book Volume: 30

Pages Range: 18405-18412

Journal Issue: 20

DOI: 10.1007/s10854-019-02194-z

Abstract

In this work, we report the influence of synthesis conditions on the (1 − x)Na0.5Bi0.5TiO3–xBaTiO3 (BNT–BT) system, obtained by the conventional solid-state reaction method with a mechanochemical activation step through two alternative synthesis routes on piezoelectric properties. Samples were characterized by X-ray diffraction (XRD), Raman microspectroscopy and scanning electron microscopy (SEM). It was confirmed that the stabilization of a morphotropic phase boundary (MPB) meaningfully improved the piezoelectric activity. Here, we report that the stabilization of the morphotropic phase boundary (MPB) region in the BNT–BT ceramic systems depended on the selected synthesis pathway. Indeed, samples prepared by the direct mechanochemical activation of all mixed BNT–BT reactants showed a correlation between dielectric and ferroelectric properties and a clear sequence in the permittivity values.

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APA:

Prado, A., Ramajo, L., Camargo, J., del Campo, A., Öchsner, P.-E., Rubio-Marcos, F., & Castro, M. (2019). Stabilization of the morphotropic phase boundary in (1 − x)Bi0.5Na0.5TiO3–xBaTiO3 ceramics through two alternative synthesis pathways. Journal of Materials Science: Materials in Electronics, 30(20), 18405-18412. https://dx.doi.org/10.1007/s10854-019-02194-z

MLA:

Prado, A., et al. "Stabilization of the morphotropic phase boundary in (1 − x)Bi0.5Na0.5TiO3–xBaTiO3 ceramics through two alternative synthesis pathways." Journal of Materials Science: Materials in Electronics 30.20 (2019): 18405-18412.

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