Anthracene-Based Receptors with a Turn-on Fluorescence Response for Nitrate

Namashivaya SS, Oshchepkov AS, Ding H, Förster S, Khrustalev VN, Kataev E (2019)

Publication Type: Journal article

Publication year: 2019

Journal

Organic Letters American Chemical Society

DOI: 10.1021/acs.orglett.9b03361

Abstract

Herein we describe the design, synthesis, and anion binding properties of bicyclic receptors with two or three anthracenes, which show a turn-on fluorescence response in the presence of nitrate and chaotropic anions in a buffered aqueous solution. The receptor with two anthracenes binds nitrate with 103 M-1 affinity and stabilizes it in the inner cavity though electrostatic, hydrogen bonding, and anion-πinteractions.

Authors with CRIS profile

Evgeny Kataev Lehrstuhl für Organische Chemie I

Involved external institutions

Technische Universität Chemnitz DE Germany (DE) Technische Universität Bergakademie Freiberg DE Germany (DE) Peoples' Friendship University of Russia (PFUR) / Российский университет дружбы народов (RUDN) RU Russian Federation (RU)

How to cite

APA:

Namashivaya, S.S., Oshchepkov, A.S., Ding, H., Förster, S., Khrustalev, V.N., & Kataev, E. (2019). Anthracene-Based Receptors with a Turn-on Fluorescence Response for Nitrate. Organic Letters. https://dx.doi.org/10.1021/acs.orglett.9b03361

MLA:

Namashivaya, Siva S.R., et al. "Anthracene-Based Receptors with a Turn-on Fluorescence Response for Nitrate." Organic Letters (2019).

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