Time-resolved analysis of dissolution phenomena in photoelectrochemistry - A case study of WO3 photocorrosion

Knoeppel J, Zhang S, Specle FD, Mayrhofer K, Scheu C, Cherevko S (2018)

Publication Status: Published

Publication Type: Journal article

Publication year: 2018

Journal

Electrochemistry Communications Elsevier

Publisher: ELSEVIER SCIENCE INC

Book Volume: 96

Pages Range: 53-56

DOI: 10.1016/j.elecom.2018.09.008

Abstract

Photocorrosion is one of the main challenges in photoelectrochemical water splitting. Traditional methods for degradation assessment, such as chronoamperometry or electrolyte/electrode post-analysis, provide limited information on the degradation mechanisms and kinetics. To address this issue, a new setup, which is based on a light source, an electrochemical cell, and an on-line inductively coupled plasma mass spectrometer (ICP-MS), has been developed. The first results on the photocorrosion of a commercial WO3 powder on Au are demonstrated in this work. It is shown that, in the absence of light, WO3 is stable in a wide potential range. On the other hand, in the presence of light, it dissolves proportionally to the anodic photocurrent. The latter is explained by the formation of aqueous tungsten complexes with the electrolyte that are thermodynamically more stable than WO3 . As can be anticipated from these initial results, the novel method will enable the characterization of a wide range of photoelectrochemical materials, and thus eventually lead to the development of long-term stable devices.

Authors with CRIS profile

Karl Mayrhofer Lehrstuhl für Elektrokatalyse (HIERN)

Involved external institutions

Forschungszentrum Jülich / Research Centre Jülich (FZJ) DE Germany (DE) Max-Planck-Institut für Eisenforschung GmbH (MPIE) / Max Planck Institute for Iron Research DE Germany (DE)

How to cite

APA:

Knoeppel, J., Zhang, S., Specle, F.D., Mayrhofer, K., Scheu, C., & Cherevko, S. (2018). Time-resolved analysis of dissolution phenomena in photoelectrochemistry - A case study of WO3 photocorrosion. Electrochemistry Communications, 96, 53-56. https://dx.doi.org/10.1016/j.elecom.2018.09.008

MLA:

Knoeppel, Julius, et al. "Time-resolved analysis of dissolution phenomena in photoelectrochemistry - A case study of WO3 photocorrosion." Electrochemistry Communications 96 (2018): 53-56.

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