Setting mechanism of a CDHA forming α-TCP cement modified with sodium phytate for improved injectability

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Details zur Publikation

Autorinnen und Autoren: Weichhold J, Gbureck U, Götz-Neunhoeffer F, Hurle K
Zeitschrift: Materials
Jahr der Veröffentlichung: 2019
Band: 12
Heftnummer: 13
ISSN: 1996-1944


Abstract

A calcium deficient hydroxyapatite (CDHA) forming cement with a bimodal grain size distribution, composed of α-TCP and fine grained CDHA at a weight ratio of 9:1, was modified by the addition of sodium phytate (IP6) in variable amounts ranging from 0.25 to 2 wt.%, related to the powder content. The injectability of the cement paste was drastically increased by the IP6 addition, independent of the amount of added IP6. Additionally, the cement paste viscosity during the first minutes decreased. These effects could be clearly related to a slightly more negative zeta potential. Furthermore, IP6 was shown to strongly retard the setting reaction, as can be seen both in the calorimetry and X-ray diffraction measurements. In addition, octacalcium phosphate (OCP) was identified as a further setting product. All measurements were performed at 23 °C and 37 °C to assess the effect of temperature on the setting reaction for both clinical handling by the surgeon and the final hardening in the bone defect.


FAU-Autorinnen und Autoren / FAU-Herausgeberinnen und Herausgeber

Götz-Neunhoeffer, Friedlinde Prof. Dr.
Lehrstuhl für Mineralogie
Hurle, Katrin Dr.
Lehrstuhl für Mineralogie


Einrichtungen weiterer Autorinnen und Autoren

Julius-Maximilians-Universität Würzburg


Zitierweisen

APA:
Weichhold, J., Gbureck, U., Götz-Neunhoeffer, F., & Hurle, K. (2019). Setting mechanism of a CDHA forming α-TCP cement modified with sodium phytate for improved injectability. Materials, 12(13). https://dx.doi.org/10.3390/ma12132098

MLA:
Weichhold, Jan, et al. "Setting mechanism of a CDHA forming α-TCP cement modified with sodium phytate for improved injectability." Materials 12.13 (2019).

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Zuletzt aktualisiert 2019-19-07 um 15:08