Electrooxidation of saturated C-1-C-3 primary alcohols on platinum: Potential-resolved product analysis with electrochemical real-time mass spectrometry (EC-RTMS)

Beitrag in einer Fachzeitschrift


Details zur Publikation

Autorinnen und Autoren: Khanipour P, Haschke S, Bachmann J, Mayrhofer KJJ, Katsounaros I
Zeitschrift: Electrochimica Acta
Jahr der Veröffentlichung: 2019
Band: 315
Seitenbereich: 67-74
ISSN: 0013-4686


Abstract

Electrochemical real-time mass spectrometry (EC-RTMS) is a novel technique for the real-time monitoring of gaseous and liquid products of electrochemical reactions, independent of their vapor pressure, with excellent temporal and potential resolution. The scope of this manuscript is to provide details on the interpretation of data for this new technique and on the assignment of mass signals to reaction products by studying three model reactions. The bulk products of the electrochemical oxidation of methanol, ethanol and 1-propanol are characterized by EC-RTMS during potentiodynamic measurements, and the capabilities of the method in detecting reaction products in real time are demonstrated. The importance of proton affinity for the detection of reaction products is highlighted. (C) 2019 Elsevier Ltd. All rights reserved.


FAU-Autorinnen und Autoren / FAU-Herausgeberinnen und Herausgeber

Bachmann, Julien Prof.
Lehrstuhl für Chemistry of thin film materials
Haschke, Sandra
Lehrstuhl für Chemistry of thin film materials


Einrichtungen weiterer Autorinnen und Autoren

Forschungszentrum Jülich GmbH (FZJ)


Zitierweisen

APA:
Khanipour, P., Haschke, S., Bachmann, J., Mayrhofer, K.J.J., & Katsounaros, I. (2019). Electrooxidation of saturated C-1-C-3 primary alcohols on platinum: Potential-resolved product analysis with electrochemical real-time mass spectrometry (EC-RTMS). Electrochimica Acta, 315, 67-74. https://dx.doi.org/10.1016/j.electacta.2019.05.070

MLA:
Khanipour, Peyman, et al. "Electrooxidation of saturated C-1-C-3 primary alcohols on platinum: Potential-resolved product analysis with electrochemical real-time mass spectrometry (EC-RTMS)." Electrochimica Acta 315 (2019): 67-74.

BibTeX: 

Zuletzt aktualisiert 2019-21-06 um 12:08