Solar energy storage at an atomically defined organic-oxide hybrid interface

Beitrag in einer Fachzeitschrift

Details zur Publikation

Autorinnen und Autoren: Schuschke C, Hohner C, Jevric M, Petersen AU, Wang Z, Schwarz M, Kettner M, Waidhas F, Fromm L, Sumby CJ, Görling A, Brummel O, Moth-Poulsen K, Libuda J
Zeitschrift: Nature Communications
Jahr der Veröffentlichung: 2019
Band: 10
ISSN: 2041-1723


Molecular photoswitches provide an extremely simple solution for solar energy conversion and storage. To convert stored energy to electricity, however, the photoswitch has to be coupled to a semiconducting electrode. In this work, we report on the assembly of an operational solar-energy-storing organic-oxide hybrid interface, which consists of a tailor-made molecular photoswitch and an atomically-defined semiconducting oxide film. The synthesized norbornadiene derivative 2-cyano-3-(4-carboxyphenyl)norbornadiene (CNBD) was anchored to a well-ordered Co3O4(111) surface by physical vapor deposition in ultrahigh vacuum. Using a photochemical infrared reflection absorption spectroscopy experiment, we demonstrate that the anchored CNBD monolayer remains operational, i.e., can be photo-converted to its energy-rich counterpart 2-cyano-3-(4-carboxyphenyl)quadricyclane (CQC). We show that the activation barrier for energy release remains unaffected by the anchoring reaction and the anchored photoswitch can be charged and discharged with high reversibility. Our atomically-defined solar-energy-storing model interface enables detailed studies of energy conversion processes at organic/oxide hybrid interfaces.

FAU-Autorinnen und Autoren / FAU-Herausgeberinnen und Herausgeber

Brummel, Olaf Dr.
Lehrstuhl für Physikalische Chemie II
Fromm, Lukas
Lehrstuhl für Theoretische Chemie
Görling, Andreas Prof. Dr.
Lehrstuhl für Theoretische Chemie
Hohner, Chantal
Lehrstuhl für Physikalische Chemie II
Kettner, Miroslav, Ph.D.
Lehrstuhl für Katalytische Grenzflächenforschung
Libuda, Jörg Prof. Dr.
Professur für Physikalische Chemie
Schuschke, Christian
Lehrstuhl für Physikalische Chemie II
Schwarz, Matthias
Lehrstuhl für Physikalische Chemie II
Waidhas, Fabian
Lehrstuhl für Physikalische Chemie II

Einrichtungen weiterer Autorinnen und Autoren

Chalmers University of Technology / Chalmers tekniska högskola
University of Adelaide


Schuschke, C., Hohner, C., Jevric, M., Petersen, A.U., Wang, Z., Schwarz, M.,... Libuda, J. (2019). Solar energy storage at an atomically defined organic-oxide hybrid interface. Nature Communications, 10.

Schuschke, Christian, et al. "Solar energy storage at an atomically defined organic-oxide hybrid interface." Nature Communications 10 (2019).


Zuletzt aktualisiert 2019-18-06 um 12:08