Electronic Communication across Porphyrin Hexabenzocoronene Isomers

Beitrag in einer Fachzeitschrift


Details zur Publikation

Autorinnen und Autoren: Martin M, Lungerich D, Haines P, Hampel F, Jux N
Zeitschrift: Angewandte Chemie International Edition
Jahr der Veröffentlichung: 2019
ISSN: 1433-7851
eISSN: 1521-3773


Abstract

Single-molecule electronic components (SMECs) are envisioned as next-generation building blocks in quantum circuit systems. However, challenges such as the reproducibility of the electrode attachment to the individual molecules hamper their fundamental investigation. For our purpose, we introduced quasi optoelectronic electrodes (QOEs) that allow for rapid investigations of the properties and suitability of compounds for molecular electronic devices. In particular, we probed hexa-peri-hexabenzocoronene (HBC) as a model system for D6h-symmetrical nanographenes, with porphyrins as QOEs attached to the periphery. We prepared selectively bis-porphyrin-functionalized HBCs with ortho-, meta- and para-substitution and studied their communication properties, in correlation to the geometrical alignment and size of the system, by electrochemistry and optical spectroscopy. Further insights into structure–property relationships were gained by DFT calculations and X-ray diffraction analysis.


FAU-Autorinnen und Autoren / FAU-Herausgeberinnen und Herausgeber

Haines, Philipp
Lehrstuhl für Physikalische Chemie I
Hampel, Frank Dr.
Lehrstuhl für Organische Chemie I
Jux, Norbert Prof. Dr.
Naturwissenschaftliche Fakultät
Lungerich, Dominik
Lehrstuhl für Organische Chemie II
Martin, Max
Lehrstuhl für Organische Chemie II


Zitierweisen

APA:
Martin, M., Lungerich, D., Haines, P., Hampel, F., & Jux, N. (2019). Electronic Communication across Porphyrin Hexabenzocoronene Isomers. Angewandte Chemie International Edition. https://dx.doi.org/10.1002/anie.201903654

MLA:
Martin, Max, et al. "Electronic Communication across Porphyrin Hexabenzocoronene Isomers." Angewandte Chemie International Edition (2019).

BibTeX: 

Zuletzt aktualisiert 2019-07-06 um 04:08