Bauer U, Fromm L, Weiß C, Späth F, Bachmann P, Düll F, Steinhauer J, Matysik S, Pominov A, Görling A, Hirsch A, Steinrück HP, Papp C (2019)
Publication Type: Journal article
Publication year: 2019
Book Volume: 150
Article Number: 184706
Journal Issue: 18
DOI: 10.1063/1.5095583
Dwindling fossil fuels force humanity to search for new energy production routes. Besides energy generation, its storage is a crucial aspect. One promising approach is to store energy from the sun chemically in strained organic molecules, so-called molecular solar thermal (MOST) systems, which can release the stored energy catalytically. A prototypical MOST system is norbornadiene/quadricyclane (NBD/QC) whose energy release and surface chemistry need to be understood. Besides important key parameters such as molecular weight, endergonic reaction profiles, and sufficient quantum yields, the position of the absorption onset of NBD is crucial to cover preferably a large range of sunlight's spectrum. For this purpose, one typically derivatizes NBD with electron-donating and/or electron-accepting substituents. To keep the model system simple enough to be investigated with photoemission techniques, we introduced bromine atoms at the 2,3-position of both compounds. We study the adsorption behavior, energy release, and surface chemistry on Ni(111) using high-resolution X-ray photoelectron spectroscopy (HR-XPS), UV photoelectron spectroscopy, and density functional theory calculations. Both Br 2 -NBD and Br 2 -QC partially dissociate on the surface at ∼120 K, with Br 2 -QC being more stable. Several stable adsorption geometries for intact and dissociated species were calculated, and the most stable structures are determined for both molecules. By temperature-programmed HR-XPS, we were able to observe the conversion of Br 2 -QC to Br 2 -NBD in situ at 170 K. The decomposition of Br 2 -NBD starts at 190 K when C-Br bond cleavage occurs and benzene and methylidene are formed. For Br 2 -QC, the cleavage already occurs at 130 K when cycloreversion to Br 2 -NBD sets in.
APA:
Bauer, U., Fromm, L., Weiß, C., Späth, F., Bachmann, P., Düll, F.,... Papp, C. (2019). Surface chemistry of 2,3-dibromosubstituted norbornadiene/quadricyclane as molecular solar thermal energy storage system on Ni(111). Journal of Chemical Physics, 150(18). https://dx.doi.org/10.1063/1.5095583
MLA:
Bauer, Udo, et al. "Surface chemistry of 2,3-dibromosubstituted norbornadiene/quadricyclane as molecular solar thermal energy storage system on Ni(111)." Journal of Chemical Physics 150.18 (2019).
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