Iodine-Pseudohalogen Ionic Liquid-Based Electrolytes for Quasi-Solid-State Dye-Sensitized Solar Cells

Lennert A, Sternberg M, Meyer K, Costa RD, Guldi DM (2017)


Publication Type: Journal article

Publication year: 2017

Journal

Book Volume: 9

Pages Range: 33437-33445

Journal Issue: 39

DOI: 10.1021/acsami.7b01522

Abstract

In the current work, novel symmetrically alkyl-substituted imidazolium-based ionic liquids have been synthesized featuring either iodide (I-) or selenocyanate (SeCN-) as counteranions. Physicochemical assays based on spectroscopy and electrochemistry techniques have been performed to identify the best ionic liquid for application as electrolytes in quasi-solid-state dye-sensitized solar cells (qssDSSC). The latter were mixed with additives such as 4-tert-butylpyridine (4tbpy) and guanidinium thiocyanate (GuSCN) to optimize electrode surface coverage, ionic diffusion, and dye regeneration. In addition, we demonstrate that electrolytes containing a mixture of I2 and (SeCN)2 enhance the open-circuit voltage of the final quasi-solid-state device by up to 70 mV. As such, iodine-pseudohalogen electrolytes reveal in qssDSSCs a good balance between dye regeneration and hole transport and, in turn, enhance the overall solar energy conversion efficiency by 70% with respect to reference qssDSSCs with iodine-based electrolytes. Finally, devices with the iodine-pseudohalogen electrolyte show a 1000 h stable efficiency of 7-8% under outdoor temperature operation conditions and 1 sun illumination.

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APA:

Lennert, A., Sternberg, M., Meyer, K., Costa, R.D., & Guldi, D.M. (2017). Iodine-Pseudohalogen Ionic Liquid-Based Electrolytes for Quasi-Solid-State Dye-Sensitized Solar Cells. ACS Applied Materials and Interfaces, 9(39), 33437-33445. https://dx.doi.org/10.1021/acsami.7b01522

MLA:

Lennert, Annkatrin, et al. "Iodine-Pseudohalogen Ionic Liquid-Based Electrolytes for Quasi-Solid-State Dye-Sensitized Solar Cells." ACS Applied Materials and Interfaces 9.39 (2017): 33437-33445.

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