Structural quantities of quasi-two-dimensional fluids
Lang S, Franosch T, Schilling R (2014)
Publication Type: Journal article
Publication year: 2014
Journal
Book Volume: 140
Article Number: 104506
Journal Issue: 10
DOI: 10.1063/1.4867284
Abstract
Quasi-two-dimensional fluids can be generated by confining a fluid between two parallel walls with narrow separation. Such fluids exhibit an inhomogeneous structure perpendicular to the walls due to the loss of translational symmetry. Taking the transversal degrees of freedom as a perturbation to an appropriate 2D reference fluid we provide a systematic expansion of the m-particle density for arbitrary m. To leading order in the slit width this density factorizes into the densities of the transversal and lateral degrees of freedom. Explicit expressions for the next-to-leading order terms are elaborated analytically quantifying the onset of inhomogeneity. The case m = 1 yields the density profile with a curvature given by an integral over the pair-distribution function of the corresponding 2D reference fluid, which reduces to its 2D contact value in the case of pure excluded-volume interactions. Interestingly, we find that the 2D limit is subtle and requires stringent conditions on the fluid-wall interactions. We quantify the rapidity of convergence for various structural quantities to their 2D counterparts.
Authors with CRIS profile
Additional Organisation(s)
Involved external institutions
Leopold-Franzens-Universität Innsbruck / University of Innsbruck
Austria (AT)
Johannes Gutenberg-Universität Mainz (JGU)
Germany (DE)
Austria (AT)
Johannes Gutenberg-Universität Mainz (JGU)
Germany (DE)
How to cite
APA:
Lang, S., Franosch, T., & Schilling, R. (2014). Structural quantities of quasi-two-dimensional fluids. Journal of Chemical Physics, 140(10). https://dx.doi.org/10.1063/1.4867284
MLA:
Lang, Simon, Thomas Franosch, and Rolf Schilling. "Structural quantities of quasi-two-dimensional fluids." Journal of Chemical Physics 140.10 (2014).
BibTeX: Download