Porphyrin-Hexaphenylbenzene Conjugates via Mixed Cyclotrimerization Reactions

Beitrag in einer Fachzeitschrift


Details zur Publikation

Autorinnen und Autoren: Martin M, Dill M, Langer J, Jux N
Zeitschrift: Journal of Organic Chemistry
Jahr der Veröffentlichung: 2019
Band: 84
Heftnummer: 3
Seitenbereich: 1489-1499
ISSN: 0022-3263


Abstract

Mixed cyclotrimerization reactions of diarylacetylenes (tolans) were applied to generate a library of multiple porphyrin-hexaphenylbenzene (HPB) architectures. Successful reactions, which could be influenced by the ratio of tolan starting materials, were conducted using dicobaltoctacarbonyl as a catalyst. Separation of the reaction products was performed by chromatographic and crystallization techniques. The physical properties were investigated with respect to the number of porphyrins per HPB and their substitution pattern.


FAU-Autorinnen und Autoren / FAU-Herausgeberinnen und Herausgeber

Jux, Norbert Prof. Dr.
Naturwissenschaftliche Fakultät
Langer, Jens Dr.
Lehrstuhl für Anorganische und Metallorganische Chemie
Martin, Max
Naturwissenschaftliche Fakultät


Zitierweisen

APA:
Martin, M., Dill, M., Langer, J., & Jux, N. (2019). Porphyrin-Hexaphenylbenzene Conjugates via Mixed Cyclotrimerization Reactions. Journal of Organic Chemistry, 84(3), 1489-1499. https://dx.doi.org/10.1021/acs.joc.8b02907

MLA:
Martin, Max, et al. "Porphyrin-Hexaphenylbenzene Conjugates via Mixed Cyclotrimerization Reactions." Journal of Organic Chemistry 84.3 (2019): 1489-1499.

BibTeX: 

Zuletzt aktualisiert 2019-04-03 um 12:08