Giant Pores in a Chromium 2,6-Naphthalenedicarboxylate Open-Framework Structure with MIL-101 Topology.

Beitrag in einer Fachzeitschrift
(Originalarbeit)


Details zur Publikation

Autorinnen und Autoren: Sonnauer A, Hoffmann F, Froeba M, Kienle L, Duppel V, Thommes M, Serre C, Ferey G, Stock N
Zeitschrift: Angewandte Chemie-International Edition
Verlag: Wiley-VCH Verlag GmbH & Co. KGaA
Jahr der Veröffentlichung: 2009
Band: 48
Heftnummer: 21
Seitenbereich: 3791-3794-3794
ISSN: 1433-7851


Abstract

Replacement of 1,4-benzenedicarboxylate by 2,6-naphthalenedicarboxylate (L) in the MIL-101 structure leads to an isoreticular mesoporous framework, [Cr3(OH)(H2O)3(μ3-O)L3]·guest (I; guest = H2O, EtOH) contg. cages with diams. of 39 and 46 Å. I was prepd. by the reaction of 2,6-naphthalenedicarboxylic acid with the Cr3+ salts, Cr(NO3)3, [Cr3(OAc)7(OH)2], CrCl3 or Cr(acac)2. High-throughput methods are employed to det. appropriate reaction conditions. The microcryst. compd. was characterized by mol. simulation techniques, powder x-ray diffraction, N2-sorption, and TEM studies. [on SciFinder(R)]


Einrichtungen weiterer Autorinnen und Autoren

Christian-Albrechts-Universität zu Kiel
Quantachrome Instruments
Universität Hamburg
Versailles Saint-Quentin-en-Yvelines University / Université de Versailles Saint-Quentin-en-Yvelines (UVSQ)


Zitierweisen

APA:
Sonnauer, A., Hoffmann, F., Froeba, M., Kienle, L., Duppel, V., Thommes, M.,... Stock, N. (2009). Giant Pores in a Chromium 2,6-Naphthalenedicarboxylate Open-Framework Structure with MIL-101 Topology. Angewandte Chemie-International Edition, 48(21), 3791-3794-3794. https://dx.doi.org/10.1002/anie.200805980

MLA:
Sonnauer, Andreas, et al. "Giant Pores in a Chromium 2,6-Naphthalenedicarboxylate Open-Framework Structure with MIL-101 Topology." Angewandte Chemie-International Edition 48.21 (2009): 3791-3794-3794.

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