Giant Pores in a Chromium 2,6-Naphthalenedicarboxylate Open-Framework Structure with MIL-101 Topology.

Sonnauer A, Hoffmann F, Froeba M, Kienle L, Duppel V, Thommes M, Serre C, Ferey G, Stock N (2009)

Publication Type: Journal article, Original article

Subtype: other

Publication year: 2009

Journal

Angewandte Chemie International Edition Wiley

Publisher: Wiley-VCH Verlag GmbH & Co. KGaA

Book Volume: 48

Pages Range: 3791-3794-3794

Journal Issue: 21

DOI: 10.1002/anie.200805980

Abstract

Replacement of 1,4-benzenedicarboxylate by 2,6-naphthalenedicarboxylate (L) in the MIL-101 structure leads to an isoreticular mesoporous framework, [Cr3(OH)(H2O)3(μ3-O)L3]·guest (I; guest = H2O, EtOH) contg. cages with diams. of 39 and 46 Å. I was prepd. by the reaction of 2,6-naphthalenedicarboxylic acid with the Cr3+ salts, Cr(NO3)3, [Cr3(OAc)7(OH)2], CrCl3 or Cr(acac)2. High-throughput methods are employed to det. appropriate reaction conditions. The microcryst. compd. was characterized by mol. simulation techniques, powder x-ray diffraction, N2-sorption, and TEM studies. [on SciFinder(R)]

Authors with CRIS profile

Matthias Thommes

Involved external institutions

Christian-Albrechts-Universität zu Kiel DE Germany (DE) Versailles Saint-Quentin-en-Yvelines University / Université de Versailles Saint-Quentin-en-Yvelines (UVSQ) FR France (FR) Universität Hamburg (UHH) DE Germany (DE) Quantachrome Instruments US United States (USA) (US)

How to cite

APA:

Sonnauer, A., Hoffmann, F., Froeba, M., Kienle, L., Duppel, V., Thommes, M.,... Stock, N. (2009). Giant Pores in a Chromium 2,6-Naphthalenedicarboxylate Open-Framework Structure with MIL-101 Topology. Angewandte Chemie International Edition, 48(21), 3791-3794-3794. https://dx.doi.org/10.1002/anie.200805980

MLA:

Sonnauer, Andreas, et al. "Giant Pores in a Chromium 2,6-Naphthalenedicarboxylate Open-Framework Structure with MIL-101 Topology." Angewandte Chemie International Edition 48.21 (2009): 3791-3794-3794.

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