A New Approach to Understand the Adsorption of Thiophene on Different Surfaces: An Atom Probe Investigation of Self-Assembled Monolayers

Eder K, Felfer P, Gault B, Ceguerra AV, La Fontaine A, Masters AF, Maschmeyer T, Cairney JM (2017)

Publication Status: Published

Publication Type: Journal article

Publication year: 2017

Journal

Langmuir American Chemical Society

Publisher: AMER CHEMICAL SOC

Book Volume: 33

Pages Range: 9573-9581

Journal Issue: 38

DOI: 10.1021/acs.langmuir.7b01820

Abstract

Atom probe tomography was used to analyze self assembled monolayers of thiophene on different surfaces, including tungsten, platinum, and aluminum, where the tungsten was examined in both pristine and oxidized forms. A glovebag with controlled atmospheres was used to alter the level of oxidation for tungsten. It was shown that different substrates lead to substantial changes in the way thiophene adsorbs on the surface. Furthermore, the oxidation of the surface strongly influenced the adsorption behavior of the thiophene molecules, leading to clear differences in the amounts and compositions of field evaporated ions and molecular ions.

Authors with CRIS profile

Peter Felfer Professur für Atom Probe Tomography

Additional Organisation(s)

Interdisziplinäres Zentrum, Center for Nanoanalysis and Electron Microscopy (CENEM) Lehrstuhl für Werkstoffwissenschaften (Allgemeine Werkstoffeigenschaften)

Involved external institutions

University of Sydney (USYD) AU Australia (AU) Max-Planck-Institut für Eisenforschung GmbH (MPIE) / Max Planck Institute for Iron Research DE Germany (DE)

How to cite

APA:

Eder, K., Felfer, P., Gault, B., Ceguerra, A.V., La Fontaine, A., Masters, A.F.,... Cairney, J.M. (2017). A New Approach to Understand the Adsorption of Thiophene on Different Surfaces: An Atom Probe Investigation of Self-Assembled Monolayers. Langmuir, 33(38), 9573-9581. https://doi.org/10.1021/acs.langmuir.7b01820

MLA:

Eder, Katja, et al. "A New Approach to Understand the Adsorption of Thiophene on Different Surfaces: An Atom Probe Investigation of Self-Assembled Monolayers." Langmuir 33.38 (2017): 9573-9581.

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