Clark T (2017)
Publication Status: Published
Publication Type: Journal article
Publication year: 2017
Publisher: ROYAL SOC CHEMISTRY
Book Volume: 203
Pages Range: 9-27
DOI: 10.1039/c7fd00058h
The models behind simple bonding theory and the origins of some components often proposed to be involved in weak intermolecular bonds are described with special reference to sigma-hole bonding, of which halogen bonds are a subset. A protocol for the analysis of weak intermolecular interactions is proposed on the basis of sound physical principles. This protocol uses three different levels of interaction; "permanent" Coulomb interactions between unperturbed monomers, relaxed Coulomb interactions and dispersion. Of the three, only dispersion is not a real, measurable quantity. It is, however, included in order to describe interactions that cannot be treated entirely by the first two levels.
APA:
Clark, T. (2017). Halogen bonds and sigma-holes. Faraday Discussions, 203, 9-27. https://dx.doi.org/10.1039/c7fd00058h
MLA:
Clark, Timothy. "Halogen bonds and sigma-holes." Faraday Discussions 203 (2017): 9-27.
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