Binary supramolecular networks of bridged triphenylamines with different substituents and identical scaffolds

Steiner C, Yang Z, Gliemann B, Meinhardt U, Gurrath M, Ammon MM, Meyer B, Kivala M, Maier S (2018)


Publication Status: Published

Publication Type: Journal article

Publication year: 2018

Journal

Publisher: ROYAL SOC CHEMISTRY

Book Volume: 54

Pages Range: 11554-11557

Journal Issue: 82

DOI: 10.1039/c8cc04410d

Abstract

Based on scanning tunneling microscopy experiments combined with density functional theory, we report the formation and the electronic structure of porous binary supramolecular networks on Au(111). The two triphenylamine derivatives with identical scaffolds intermix due to a maximization of the overall number of H-bonds instead of an optimization of the H-bond strength in the bonding motif. The HOMO-LUMO gap is defined by both molecules, which is typical for electron donor-acceptor networks.

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APA:

Steiner, C., Yang, Z., Gliemann, B., Meinhardt, U., Gurrath, M., Ammon, M.M.,... Maier, S. (2018). Binary supramolecular networks of bridged triphenylamines with different substituents and identical scaffolds. Chemical Communications, 54(82), 11554-11557. https://dx.doi.org/10.1039/c8cc04410d

MLA:

Steiner, Christian, et al. "Binary supramolecular networks of bridged triphenylamines with different substituents and identical scaffolds." Chemical Communications 54.82 (2018): 11554-11557.

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