Sensory characterization and identification of odorous constituents in acrylic adhesives

Beitrag in einer Fachzeitschrift


Details zur Publikation

Autor(en): Denk P, Büttner AK
Zeitschrift: International Journal of Adhesion and Adhesives
Verlag: ELSEVIER SCI LTD
Jahr der Veröffentlichung: 2017
Band: 78
Seitenbereich: 182-188
ISSN: 0143-7496


Abstract

Most products in our surroundings contain adhesives, including acrylic adhesives which are used in many industry sectors. Some of these adhesives contain solvents that produce strong odors, but even adhesives which are produced without solvents can emit intensive or pungent odors. In the latter case, the odor may arise from monomers in the adhesive product, from manufacturing by-products or from degradation products. Here we analyzed several acrylic, methacrylic and benzyl acrylic adhesives to identify representative odorous contaminants. The volatile fraction of the products was extracted and isolated by solvent-assisted flavor evaporation (SAFE), then analyzed via high-resolution gas chromatography olfactometry (HRGC-O), HRGC-mass spectrometry (HRGC-MS/O) and two-dimensional HRGC-MS/O. Aroma extract dilution analysis was carried out to determine the most prominent odorants. Using this targeted odorant-analytical approach, we identified 27 odorous substances representing diverse classes of molecules, including phenols with leather-like, horse stable like or medicinal odors, acrylates eliciting glue-like, moldy and fruity impressions, and different esters with honey-like or effervescent tablet-like smells. These results show that the odor of acrylic adhesives results from a mixture of different odorants that cannot generally be traced back to the main constituents of the product but are rather likely to stem from impurities and trace side products and other contaminants.


FAU-Autoren / FAU-Herausgeber

Büttner, Andrea Prof. Dr.
Professur für Aromaforschung
Denk, Philipp
Professur für Aromaforschung


Zitierweisen

APA:
Denk, P., & Büttner, A.K. (2017). Sensory characterization and identification of odorous constituents in acrylic adhesives. International Journal of Adhesion and Adhesives, 78, 182-188. https://dx.doi.org/10.1016/j.ijadhadh.2017.06.020

MLA:
Denk, Philipp, and Andrea Karin Büttner. "Sensory characterization and identification of odorous constituents in acrylic adhesives." International Journal of Adhesion and Adhesives 78 (2017): 182-188.

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Zuletzt aktualisiert 2018-23-08 um 10:53