Designed To React: Terminal Copper Nitrenes and Their Application in Catalytic C-H Aminations.

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Details zur Publikation

Autor(en): Moegling J, Hoffmann A, Thomas F, Orth N, Liebhaeuser P, Herber U, Rampmaier R, Stanek J, Fink G, Ivanovic-Burmazovic I, Herres-Pawlis S
Zeitschrift: Angewandte Chemie-International Edition
Jahr der Veröffentlichung: 2018
ISSN: 1433-7851


Abstract

tBuPhINTs and copper(I) acetonitrile complexes. Their stoichiometric reactivity has been elucidated regarding the imination of phosphines and the aziridination of styrenes. The formation and thermal decay of the copper nitrenes were investigated by UV/Vis spectroscopy of the highly coloured species. Additionally, the compounds were studied by cryo-UHR-ESI mass spectrometry and DFT calculations. In addition, a mild catalytic procedure has been developed where the copper nitrene precursors enable the C-H amination of cyclohexane and toluene and the aziridination of styrenes.


FAU-Autoren / FAU-Herausgeber

Ivanovic-Burmazovic, Ivana Prof. Dr.
Lehrstuhl für Bioanorganische Chemie
Orth, Nicole
Lehrstuhl für Bioanorganische Chemie


Autor(en) der externen Einrichtung(en)
Ludwig-Maximilians-Universität (LMU)
Rheinisch-Westfälische Technische Hochschule (RWTH) Aachen


Zitierweisen

APA:
Moegling, J., Hoffmann, A., Thomas, F., Orth, N., Liebhaeuser, P., Herber, U.,... Herres-Pawlis, S. (2018). Designed To React: Terminal Copper Nitrenes and Their Application in Catalytic C-H Aminations. Angewandte Chemie-International Edition. https://dx.doi.org/10.1002/anie.201713171

MLA:
Moegling, Julian, et al. "Designed To React: Terminal Copper Nitrenes and Their Application in Catalytic C-H Aminations." Angewandte Chemie-International Edition (2018).

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Zuletzt aktualisiert 2018-01-08 um 13:08