Designed To React: Terminal Copper Nitrenes and Their Application in Catalytic C-H Aminations.

Moegling J, Hoffmann A, Thomas F, Orth N, Liebhaeuser P, Herber U, Rampmaier R, Stanek J, Fink G, Ivanovic-Burmazovic I, Herres-Pawlis S (2018)


Publication Status: Published

Publication Type: Journal article

Publication year: 2018

Journal

DOI: 10.1002/anie.201713171

Abstract

tBuPhINTs and copper(I) acetonitrile complexes. Their stoichiometric reactivity has been elucidated regarding the imination of phosphines and the aziridination of styrenes. The formation and thermal decay of the copper nitrenes were investigated by UV/Vis spectroscopy of the highly coloured species. Additionally, the compounds were studied by cryo-UHR-ESI mass spectrometry and DFT calculations. In addition, a mild catalytic procedure has been developed where the copper nitrene precursors enable the C-H amination of cyclohexane and toluene and the aziridination of styrenes.

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APA:

Moegling, J., Hoffmann, A., Thomas, F., Orth, N., Liebhaeuser, P., Herber, U.,... Herres-Pawlis, S. (2018). Designed To React: Terminal Copper Nitrenes and Their Application in Catalytic C-H Aminations. Angewandte Chemie International Edition. https://dx.doi.org/10.1002/anie.201713171

MLA:

Moegling, Julian, et al. "Designed To React: Terminal Copper Nitrenes and Their Application in Catalytic C-H Aminations." Angewandte Chemie International Edition (2018).

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