Acenequinocumulenes: Lateral and vertical π-extended analogs of tetracyanoquinodimethane (TCNQ)

Gruber M, Padberg K, Min J, Waterloo A, Hampel F, Maid H, Ameri T, Brabec C, Tykwinski R (2017)


Publication Language: English

Publication Type: Journal article, Original article

Publication year: 2017

Journal

Book Volume: 23

Pages Range: 17829-17835

Journal Issue: 70

DOI: 10.1002/chem.201704314

Abstract

We have designed a series of molecules and developed synthetic methodology that
allows for the inclusion of structural diversity along both the lateral and vertical axes of the
basic TCNQ skeleton. In the lateral direction, benzoannulation extends the π-system through
(hetero)acene formation, while incorporation of a [3]cumulene increases delocalization
vertically. The potential of these new molecules as semiconductors is explored through
UV-vis spectroscopy, cyclic voltammetry, X-ray crystallography, thin film formation, and
mobility measurements (via space charge limited current measurements).

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APA:

Gruber, M., Padberg, K., Min, J., Waterloo, A., Hampel, F., Maid, H.,... Tykwinski, R. (2017). Acenequinocumulenes: Lateral and vertical π-extended analogs of tetracyanoquinodimethane (TCNQ). Chemistry - A European Journal, 23(70), 17829-17835. https://dx.doi.org/10.1002/chem.201704314

MLA:

Gruber, Marco, et al. "Acenequinocumulenes: Lateral and vertical π-extended analogs of tetracyanoquinodimethane (TCNQ)." Chemistry - A European Journal 23.70 (2017): 17829-17835.

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