Co-solvent intensification effect on aromatic alcohol oxidation

Beitrag in einer Fachzeitschrift


Details zur Publikation

Autor(en): Chen L, Chen L, Ye Y, Qi Z, Freund H, Sundmacher K
Zeitschrift: Catalysis Communications
Verlag: Elsevier
Jahr der Veröffentlichung: 2012
Band: 28
Seitenbereich: 143-146
ISSN: 1566-7367


Abstract


Solvent intensification for aromatic alcohol oxidation was performed by experimentally extensive screening. A co-solvent mixture of[Omim]Cl and toluene was found to significantly intensify this class of reactions with high conversion of alcohols (>90%) and high selectivity to their aldehydes (>90%). The intensification effect can be jointly attributed to the interaction of [Omim]Cl with the catalyst WO3 surface, which enhances its catalytic reactivity, and to the aqueous-organic biphasic formation by toluene, which inhibits the over-oxidation of aromatic alcohols. (C) 2012 Elsevier B.V. All rights reserved.



FAU-Autoren / FAU-Herausgeber

Freund, Hannsjörg Prof. Dr.
Professur für Katalytische Reaktoren und Prozesstechnik


Autor(en) der externen Einrichtung(en)
East China University of Science and Technology (ECUST)
Max-Planck-Institut für Dynamik komplexer technischer Systeme / Max Planck Institute for Dynamics of Complex Technical Systems


Zitierweisen

APA:
Chen, L., Chen, L., Ye, Y., Qi, Z., Freund, H., & Sundmacher, K. (2012). Co-solvent intensification effect on aromatic alcohol oxidation. Catalysis Communications, 28, 143-146. https://dx.doi.org/10.1016/j.catcom.2012.08.029

MLA:
Chen, Long, et al. "Co-solvent intensification effect on aromatic alcohol oxidation." Catalysis Communications 28 (2012): 143-146.

BibTeX: 

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