Bicyclic diironcryptates with mobile guest cations: A new class of solid ionic conductors
Puchta R, Roling B, Scheurer A, Weiskopf V, Hampel F, van Eikema Hommes N, Hummel HU (2008)
Publication Status: Published
Publication Type: Journal article
Publication year: 2008
Journal
Publisher: Elsevier
Book Volume: 179
Pages Range: 489-494
Journal Issue: 13-14
DOI: 10.1016/j.ssi.2008.02.060
Abstract
Polycrystalline bicyclic diironcryptates with different mobile guest cations were synthesized and characterized by XRD analysis, IR spectroscopy, FAB-mass spectroscopy, elemental analysis, electrical conductivity spectroscopy and ion exchange experiments. We find strong indication that the guest cations exhibit a long-range mobility and that their mobility is governed by their size relative to the size of the cryptand molecules. On the other hand, the valence of the guest cations seems to play a minor role for the mobility. These results are discussed in comparison to the properties of conventional solid cationic conductors. (c) 2008 Elsevier B.V. All rights reserved.
Authors with CRIS profile
Ralph Puchta
Naturwissenschaftliche Fakultät
Andreas Scheurer
Lehrstuhl für Anorganische und Allgemeine Chemie
Frank Hampel
Lehrstuhl für Organische Chemie I
Nicolaas van Eikema Hommes
Computer-Chemie-Centrum (CCC)
Involved external institutions
Germany (DE)How to cite
APA:
Puchta, R., Roling, B., Scheurer, A., Weiskopf, V., Hampel, F., van Eikema Hommes, N., & Hummel, H.-U. (2008). Bicyclic diironcryptates with mobile guest cations: A new class of solid ionic conductors. Solid State Ionics, 179(13-14), 489-494. https://doi.org/10.1016/j.ssi.2008.02.060
MLA:
Puchta, Ralph, et al. "Bicyclic diironcryptates with mobile guest cations: A new class of solid ionic conductors." Solid State Ionics 179.13-14 (2008): 489-494.
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