A Rhodium Triphenylphosphine Catalyst for Alkene Hydrogenation Supported on Neat Superparamagnetic Iron Oxide Nanoparticles

Dehe D, Wang L, Mueller MK, Doerr G, Zhou Z, Klupp-Taylor RN, Sun Y, Ernst S, Hartmann M, Bauer M, Thiel WR, Klupp Taylor R (2015)


Publication Status: Published

Publication Type: Journal article, Original article

Publication year: 2015

Journal

Publisher: Wiley-VCH Verlag

Book Volume: 7

Pages Range: 127-136

Journal Issue: 1

DOI: 10.1002/cctc.201402615

Abstract

A phosphonic acid functionalized triphenylphosphine rhodium complex was synthesized and grafted onto neat superparamagnetic iron oxide nanoparticles. The material was investigated by elemental analysis, IR spectroscopy, thermogravimetric analysis, XRD, N-2-physisorption analyses, and TEM measurements. The obtained hybrid material could be used as a catalyst for the hydrogenation of alkenes with excellent yields and a broad substrate scope. The catalyst can be reused ten times without any loss of activity. According to the results from X-ray absorption spectroscopy, it is likely that formation of Rh nanoparticles occurs during the reaction.

Authors with CRIS profile

Related research project(s)

Involved external institutions

How to cite

APA:

Dehe, D., Wang, L., Mueller, M.K., Doerr, G., Zhou, Z., Klupp-Taylor, R.N.,... Klupp Taylor, R. (2015). A Rhodium Triphenylphosphine Catalyst for Alkene Hydrogenation Supported on Neat Superparamagnetic Iron Oxide Nanoparticles. ChemCatChem, 7(1), 127-136. https://dx.doi.org/10.1002/cctc.201402615

MLA:

Dehe, Daniel, et al. "A Rhodium Triphenylphosphine Catalyst for Alkene Hydrogenation Supported on Neat Superparamagnetic Iron Oxide Nanoparticles." ChemCatChem 7.1 (2015): 127-136.

BibTeX: Download