Selective catalytic conversion of biobased carbohydrates to formic acid using molecular oxygen

Beitrag in einer Fachzeitschrift


Details zur Publikation

Autor(en): Woelfel R, Taccardi N, Bösmann A, Wasserscheid P
Zeitschrift: Green Chemistry
Verlag: Royal Society of Chemistry
Jahr der Veröffentlichung: 2011
Band: 13
Heftnummer: 10
Seitenbereich: 2759--2763
ISSN: 1463-9262
eISSN: 1463-9270


Abstract


A new and straightforward method to transform carbohydrate-based biomass to formic acid (FA) by oxidation with molecular oxygen in aqueous solution using a Keggin-type H5PV2Mo10O40 polyoxometalate as catalyst is presented. Several water-soluble carbohydrates were fully and selectively converted to formic acid and CO2 under very mild conditions. It is worth noting, even complex biomass mixtures, such as poplar wood sawdust, were transformed to formic acid, giving 19 wt{\%} yield (11{\%} based on the carbon atoms in the feedstock) under non-optimized conditions.



FAU-Autoren / FAU-Herausgeber

Bösmann, Andreas Dr.
Lehrstuhl für Chemische Reaktionstechnik
Taccardi, Nicola Dr.
Lehrstuhl für Chemische Reaktionstechnik
Wasserscheid, Peter Prof. Dr.
Lehrstuhl für Chemische Reaktionstechnik
Woelfel, Rene
Lehrstuhl für Chemische Reaktionstechnik


Zusätzliche Organisationseinheit(en)
Exzellenz-Cluster Engineering of Advanced Materials


Zitierweisen

APA:
Woelfel, R., Taccardi, N., Bösmann, A., & Wasserscheid, P. (2011). Selective catalytic conversion of biobased carbohydrates to formic acid using molecular oxygen. Green Chemistry, 13(10), 2759--2763. https://dx.doi.org/10.1039/C1GC15434F

MLA:
Woelfel, Rene, et al. "Selective catalytic conversion of biobased carbohydrates to formic acid using molecular oxygen." Green Chemistry 13.10 (2011): 2759--2763.

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Zuletzt aktualisiert 2018-08-09 um 07:10