Organophosphorus compounds; 122. Alkylation of 1H-phosphirenes with triflates - Synthesis of lambda(5)sigma(4)-1H-phosphirenium cations
Göller AH, Clark T (1998)
Publication Status: Published
Publication Type: Journal article
Publication year: 1998
Journal
Publisher: Thieme Publishing / Georg Thieme Verlag
Pages Range: 175-180
Journal Issue: 2
DOI: 10.1055/s-1998-2010
Abstract
The 1H-phosphirenes 9a-g were alkylated by the trifluoromethanesulfonate esters 10a,b to furnish the stable phosphirenium salts 11a-i. The phosphirenium salts 14 bearing two identical exocyclic substituents at phosphorus were obtained by reactions of the silyl-substituted 1H-phosphirene 12 with a twofold molar amount of the esters 10a,b. As examples for the reactivity, the salts 11b,d were subjected to hydrolysis (--> 15a,b) and 11c to methanolysis (--> 16).
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APA:
Göller, A.H., & Clark, T. (1998). Organophosphorus compounds; 122. Alkylation of 1H-phosphirenes with triflates - Synthesis of lambda(5)sigma(4)-1H-phosphirenium cations. Synthesis-Stuttgart, 2, 175-180. https://doi.org/10.1055/s-1998-2010
MLA:
Göller, Andreas H., and Timothy Clark. "Organophosphorus compounds; 122. Alkylation of 1H-phosphirenes with triflates - Synthesis of lambda(5)sigma(4)-1H-phosphirenium cations." Synthesis-Stuttgart 2 (1998): 175-180.
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