1H-phosphiranes and -enes invert at phosphorus via a turnstile rotation

Göller AH, Clark T (1997)

Publication Status: Published

Publication Type: Journal article

Publication year: 1997

Journal

Chemical Communications Royal Society of Chemistry

Publisher: Royal Society of Chemistry

Pages Range: 1033-1034

Journal Issue: 11

DOI: 10.1039/a701788j

Abstract

Ab initio (CCSD(T)/6-31+G*) calculations suggest that 1H-phosphiranes and 1H-phosphirenes invert their configuration at phosphorus by a rotation of the PX group (X = H, F, Cl, Br) above the C-2 moiety, rather than the more usual planar trigonal inversion pathway via a C-2v transition state.

Authors with CRIS profile

Timothy Clark Computer-Chemie-Centrum

Involved external institutions

Bayer HealthCare AG DE Germany (DE)

How to cite

APA:

Göller, A.H., & Clark, T. (1997). 1H-phosphiranes and -enes invert at phosphorus via a turnstile rotation. Chemical Communications, 11, 1033-1034. https://dx.doi.org/10.1039/a701788j

MLA:

Göller, Andreas H., and Timothy Clark. "1H-phosphiranes and -enes invert at phosphorus via a turnstile rotation." Chemical Communications 11 (1997): 1033-1034.

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