Probing a gas/liquid acid-base reaction by X-ray photoelectron spectroscopy

Niedermaier I, Taccardi N, Wasserscheid P, Maier F, Steinrück HP (2013)


Publication Type: Journal article

Publication year: 2013

Journal

Original Authors: Niedermaier I., Taccardi N., Wasserscheid P., Maier F., Steinrück H.-P.

Publisher: Wiley-VCH Verlag

Book Volume: 52

Pages Range: 8904-8907

Journal Issue: 34

DOI: 10.1002/anie.201304115

Abstract

A mechanistic study: In a Brønsted acid/base reaction, gaseous triflic acid (OTfH) transfers its proton to the basic Cl anion of the ionic liquid [CCIm]Cl forming volatile HCl and the IL [CCIm][TfO]. This anion exchange reaction is monitored in the near-surface region quantitatively by X-ray photoelectron spectroscopy as a function of time (see picture; BE=binding energy). Copyright © 2013 WILEY-VCH Verlag GmbH & Co. KGaA, Weinheim.

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APA:

Niedermaier, I., Taccardi, N., Wasserscheid, P., Maier, F., & Steinrück, H.-P. (2013). Probing a gas/liquid acid-base reaction by X-ray photoelectron spectroscopy. Angewandte Chemie International Edition, 52(34), 8904-8907. https://dx.doi.org/10.1002/anie.201304115

MLA:

Niedermaier, Inga, et al. "Probing a gas/liquid acid-base reaction by X-ray photoelectron spectroscopy." Angewandte Chemie International Edition 52.34 (2013): 8904-8907.

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