Ethene/Ethane and Propene/Propane Separation via the Olefin and Paraffin Selective Metal-Organic Framework Adsorbents CPO-27 and ZIF-8

Böhme U, Barth B, Paula C, Kuhnt A, Schwieger W, Mundstock A, Caro J, Hartmann M, Hartmann M (2013)


Publication Status: Published

Publication Type: Journal article

Publication year: 2013

Journal

Publisher: American Chemical Society

Book Volume: 29

Pages Range: 8592-8600

DOI: 10.1021/la401471g

Abstract

Two types of metal-organic frameworks (MOFs) have been synthesized and evaluated in the separation of C-2 and C-3 olefins and paraffins; Whereas Co-2(dhtp) (=Co-CPO-27 = Co-MOF-74) and Mg-2(dhtp) show an adsorption selectivity for the olefins ethene and propene over the paraffins ethane and propane, the zeolitic imidazolate framework ZIF-8 behaves in the opposite way and preferentially adsorbs the alkane. Consequently, in break-through experiments, the olefins or paraffins, respectively, can be separated.

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How to cite

APA:

Böhme, U., Barth, B., Paula, C., Kuhnt, A., Schwieger, W., Mundstock, A.,... Hartmann, M. (2013). Ethene/Ethane and Propene/Propane Separation via the Olefin and Paraffin Selective Metal-Organic Framework Adsorbents CPO-27 and ZIF-8. Langmuir, 29, 8592-8600. https://doi.org/10.1021/la401471g

MLA:

Böhme, Ulrike, et al. "Ethene/Ethane and Propene/Propane Separation via the Olefin and Paraffin Selective Metal-Organic Framework Adsorbents CPO-27 and ZIF-8." Langmuir 29 (2013): 8592-8600.

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