Ethene/Ethane and Propene/Propane Separation via the Olefin and Paraffin Selective Metal-Organic Framework Adsorbents CPO-27 and ZIF-8
Böhme U, Barth B, Paula C, Kuhnt A, Schwieger W, Mundstock A, Caro J, Hartmann M, Hartmann M (2013)
Publication Status: Published
Publication Type: Journal article
Publication year: 2013
Journal
Publisher: American Chemical Society
Book Volume: 29
Pages Range: 8592-8600
DOI: 10.1021/la401471g
Abstract
Two types of metal-organic frameworks (MOFs) have been synthesized and evaluated in the separation of C-2 and C-3 olefins and paraffins; Whereas Co-2(dhtp) (=Co-CPO-27 = Co-MOF-74) and Mg-2(dhtp) show an adsorption selectivity for the olefins ethene and propene over the paraffins ethane and propane, the zeolitic imidazolate framework ZIF-8 behaves in the opposite way and preferentially adsorbs the alkane. Consequently, in break-through experiments, the olefins or paraffins, respectively, can be separated.
Authors with CRIS profile
Ulrike Böhme
Interdisziplinäres Zentrum Erlangen Catalysis Resource Center (ECRC)
Benjamin Barth
Interdisziplinäres Zentrum Erlangen Catalysis Resource Center (ECRC)
Carolin Paula
Interdisziplinäres Zentrum Erlangen Catalysis Resource Center (ECRC)
Andreas Kuhnt
Professur für Technische Chemie (Reaktionstechnik)
Wilhelm Schwieger
Professur für Technische Chemie (Reaktionstechnik)
Martin Hartmann
Professur für Katalyse
Involved external institutions
Germany (DE)How to cite
APA:
Böhme, U., Barth, B., Paula, C., Kuhnt, A., Schwieger, W., Mundstock, A.,... Hartmann, M. (2013). Ethene/Ethane and Propene/Propane Separation via the Olefin and Paraffin Selective Metal-Organic Framework Adsorbents CPO-27 and ZIF-8. Langmuir, 29, 8592-8600. https://dx.doi.org/10.1021/la401471g
MLA:
Böhme, Ulrike, et al. "Ethene/Ethane and Propene/Propane Separation via the Olefin and Paraffin Selective Metal-Organic Framework Adsorbents CPO-27 and ZIF-8." Langmuir 29 (2013): 8592-8600.
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