Model-based prediction of optimal conditions for 1-octene hydroformylation

Beitrag in einer Fachzeitschrift


Details zur Publikation

Autor(en): Hentschel B, Peschel A, Xie M, Vogelpohl C, Sadowski G, Freund H, Sundmacher K
Zeitschrift: Chemical Engineering Science
Verlag: Elsevier
Jahr der Veröffentlichung: 2014
Band: 115
Seitenbereich: 58-68
ISSN: 0009-2509


Abstract


After fitting the PC-SAFT parameters to pure component data the model was used to study the influence of product formation on the solubilities of H-2 and CO. Finally, the reaction conditions were optimized in order to maximize the differential selectivity to the desired product n-nonanal. It is shown that the performance of the hydroformylation reaction system can be significantly increased by optimally controlling temperature, total pressure, and the amount of H-2 and CO in the gas phase. (C) 2013 Elsevier Ltd. All rights reserved.



FAU-Autoren / FAU-Herausgeber

Freund, Hannsjörg Prof. Dr.
Professur für Katalytische Reaktoren und Prozesstechnik


Autor(en) der externen Einrichtung(en)
Max-Planck-Institut für Dynamik komplexer technischer Systeme / Max Planck Institute for Dynamics of Complex Technical Systems
Otto-von-Guericke-Universität Magdeburg
Technische Universität Dortmund


Zitierweisen

APA:
Hentschel, B., Peschel, A., Xie, M., Vogelpohl, C., Sadowski, G., Freund, H., & Sundmacher, K. (2014). Model-based prediction of optimal conditions for 1-octene hydroformylation. Chemical Engineering Science, 115, 58-68. https://dx.doi.org/10.1016/j.ces.2013.03.051

MLA:
Hentschel, Benjamin, et al. "Model-based prediction of optimal conditions for 1-octene hydroformylation." Chemical Engineering Science 115 (2014): 58-68.

BibTeX: 

Zuletzt aktualisiert 2018-10-08 um 05:25