Synthesis and characterization of cerium and yttrium alkoxide complexes supported by ferrocene-based chelating ligands

Broderick EM, Thuy-Boun PS, Guo N, Vogel C, Sutter J, Miller JT, Meyer K, Diaconescu PL (2011)

Publication Type: Journal article, Original article

Publication year: 2011

Journal

Inorganic Chemistry American Chemical Society

Original Authors: Broderick E.M., Thuy-Boun P.S., Guo N., Vogel C.S., Sutter J., Miller J.T., Meyer K., Diaconescu P.L.

Publisher: American Chemical Society

Book Volume: 50

Pages Range: 2870-2877

Journal Issue: 7

DOI: 10.1021/ic102076g

Abstract

Two series of Schiff base metal complexes were investigated, where each series was supported by an ancillary ligand incorporating a ferrocene backbone and different N=X functionalities. One ligand is based on an imine, while the other is based on an iminophosphorane group. Cerium(IV), cerium(III), and yttrium(III) alkoxide complexes supported by the two ligands were synthesized. All metal complexes were characterized by cyclic voltammetry. Additionally, NMR, Mössbauer, X-ray absorption near-edge structure (XANES), and absorption spectroscopies were used. The experimental data indicate that iron remains in the +2 oxidation state and that cerium(IV) does not engage in a redox behavior with the ancillary ligand. © 2011 American Chemical Society.

Authors with CRIS profile

Carola Vogel Lehrstuhl für Anorganische und Allgemeine Chemie Jörg Sutter Lehrstuhl für Anorganische und Allgemeine Chemie Karsten Meyer Lehrstuhl für Anorganische und Allgemeine Chemie

Involved external institutions

University of California Los Angeles (UCLA) US United States (USA) (US) Argonne National Laboratory US United States (USA) (US)

How to cite

APA:

Broderick, E.M., Thuy-Boun, P.S., Guo, N., Vogel, C., Sutter, J., Miller, J.T.,... Diaconescu, P.L. (2011). Synthesis and characterization of cerium and yttrium alkoxide complexes supported by ferrocene-based chelating ligands. Inorganic Chemistry, 50(7), 2870-2877. https://dx.doi.org/10.1021/ic102076g

MLA:

Broderick, Erin M., et al. "Synthesis and characterization of cerium and yttrium alkoxide complexes supported by ferrocene-based chelating ligands." Inorganic Chemistry 50.7 (2011): 2870-2877.

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