Gross B, Schurig V, Lamparth I, Hirsch A (1997)
Publication Type: Journal article, Original article
Publication year: 1997
Original Authors: Gross B., Schurig V., Lamparth I., Hirsch A.
Publisher: Elsevier
Book Volume: 791
Pages Range: 65-69
DOI: 10.1016/S0021-9673(97)00818-2
The enantiomer separation of [60]fullerene derivatives on the chiral stationary phase (CSP) (R)-(-)-2-(2,4,5,7-tetranitro-9- fluorenylideneaminooxy) propionic acid (TAPA) was achieved. A [60]fullerene tris- and hexakis-adduct with achiral addends and an inherent chiral addition pattern were separated on a micro HPLC column containing R-(-)-TAPA bonded to silica gel as CSP. The stationary phase exhibits an intermediate polarity and separations were performed using the normal and reversed-phase mode. With the hexakis-adduct, near-baseline separation was achieved. The tris-adduct shows a strong interaction with the CSP expressed by a high retention factor but inferior enantiomer separation.
APA:
Gross, B., Schurig, V., Lamparth, I., & Hirsch, A. (1997). Enantiomer separation of [60]fullerene derivatives by micro-column high- performance liquid chromatography using (R)-(-)-2-(2,4,5,7-tetranitro-9- fluorenylideneaminooxy) propionic acid as chiral stationary phase. Journal of Chromatography A, 791, 65-69. https://dx.doi.org/10.1016/S0021-9673(97)00818-2
MLA:
Gross, Birgit, et al. "Enantiomer separation of [60]fullerene derivatives by micro-column high- performance liquid chromatography using (R)-(-)-2-(2,4,5,7-tetranitro-9- fluorenylideneaminooxy) propionic acid as chiral stationary phase." Journal of Chromatography A 791 (1997): 65-69.
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