Hanack M, Hirsch A, Lange A, Rein M, Renz G, Vermehren P (1991)
Publication Type: Journal article, Original article
Publication year: 1991
Original Authors: Hanack Michael, Hirsch A., Lange A., Rein M., Renz G., Vermehren P.
Publisher: Cambridge University Press (CUP) / Materials Research Society
Book Volume: 6
Pages Range: 385-392
Journal Issue: 2
Bridged quasi-one-dimensional macrocyclic transition metal complexes [MacM(L)] using phthalocyanine (Pc) tetrabenzoporphyrine (TBP), 1,2- and 2,3-naphthalocyanines (1,2-Nc; 2,3-Nc) as macrocycles (Mac) with M = e.g., Fe, Ru, Co and L = e.g., pyrazine (pyz), 1,4-diisocyanobenzene (dib), tetrazine (tz) exhibit interesting electrical properties. Regardless of the size of the bridging ligand after either chemical or electrochemical doping stable semiconducting compounds [MacM(L)X] (X = e.g., I BF, ClO...) are formed. For the first time the complete characterization of soluble oligomers [MacM(L)] (Mac = t-BuPc, M = Ru, L = dib, medib) by H-NMR spectroscopy is reported. Some of these shish kebab complexes, e.g., [PcM(tz)], (M = Fe, Ru) or [MacMCN[; (Mac = Pc, TBP; M = Co,Fe) exhibit good semiconducting properties without additional external doping. Whether or not these compounds are intrinsic semiconductors will be discussed. The synthesis of oligomeric bridged mixed valence compounds [PcM(III)LPcM(II)L] (M = e.g., Fe) is another target of our work. We report here on first results of these oligomers.
APA:
Hanack, M., Hirsch, A., Lange, A., Rein, M., Renz, G., & Vermehren, P. (1991). Bridged macrocyclic transition metal complexes, a new type of semiconducting materials. Journal of Materials Research, 6(2), 385-392. https://doi.org/10.1557/JMR.1991.0385
MLA:
Hanack, Michael, et al. "Bridged macrocyclic transition metal complexes, a new type of semiconducting materials." Journal of Materials Research 6.2 (1991): 385-392.
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